What is the national library of scotland? The National Library of Scotland is Scotland's largest library and the world centre for the study of Scotland and the Scots.How do i contact the library of wales? Email: enquiry(at)llgc.org.uk; Telephone: +44 (0)1970 632 933 (9.30-17.00) Fax +44 (0)1970 632 551; Writing to the Enquiries Service, The National Library of Wales, Aberystwyth, Ceredigion. SY23 3BU; The National Library of Wales offers a free enquiry answering service, and enquirers are welcome to contact us with their questions.How do i contact the national museum of scotland? Contact: email [email protected] or call 0131 247 4041. If you’re planning to visit the National Museum of Scotland as part of a group, please let us know you’re coming! Whether you're a school group, a society or special interest group, we will be delighted to work with you to plan your visit.Will the library contact me about my use of the library? The Library will only contact you, if necessary, regarding your use of the Library or your library card. Required field. Required field. Please confirm your education affiliation. This is required to ensure we comply with the licences of the electronic resources we offer. Learn more about ways to support the National Library of Scotland.