Where is the corporate headquarters of valero energy? Valero signage at corporate headquarters. Valero Energy Corporation is a Fortune 500 international manufacturer and marketer of transportation fuels, other petrochemical products, and power. It is headquartered in San Antonio, Texas, United States.What is valero refining and marketing company? In May 1985, Valero Refining and Marketing Company was born from Valero's subsidiary, Saber Energy, Inc. In 1997, Valero Energy Company, "Energy," spun off its subsidiary, Valero, to its stockholders.Why work at valero? We care about health and safety, and protecting our employees and neighbors. Valero, through its subsidiaries, owns 15 petroleum refineries in the United States, Canada and the United Kingdom and owns 14 ethanol process plants in the United States.
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